Utilisation des micro-ondes dans la synthèse de nouveaux hétérocycles azépiniques à partir de l’isophorone
Written by sctunisie no commentsNew caprolactams and related compounds were synthesized via Beckmann rearrangements and subsequent Diels-Alder additions starting from ketone oximes of isophorone derivatives. The reactions were activated by microwave irradiation and the results were compared to those obtained under conventional heating. Anyhow, microwave activation was more efficient as compared to conventional heating, every conditions equal elsewhere.
Y. El Barkaoui, A. El Louzil, A. Loupy, M. Soufiaoui, S. Fkih-Tetouani
Microwave, isophorone, caprolactames, azipines, rearrangement de Beckmann, addition de Diels-Alder
Pages 1571-1576
