JOURNAL of the Tunisian Chemical Society

serving the Research, the Education and the Industry

Action of hydrazines on ketoaldehydephosphonates: Synthesis of β-phosphocycloalcanepyrazoles

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A variety of ketoaldehydphosphonates 2 have been prepared by reaction of γ-ketophosphonates 1 with ethylformate in basic conditions. On reaction with hydrazines, compounds 2 lead to β-phosphocycloalcanepyrazoles 3. The structure of all obtained products was determined on the basis of their IR and NMR data.

S. Touil, H. Zantour

Ketones γ-phosphonates, ketoaldehydephosphonates, β-phosphocycloalcanepyrazoles, RMN 1H, RMN 31P, RMN 13C

Pages 371-377

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