JOURNAL of the Tunisian Chemical Society

serving the Research, the Education and the Industry

Synthesis and reactivity of azaspiropentanes

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Condensation of diphenylsulfonium cyclopropylide with diary] and arylalkylimines generates azaspiropentanes. Solvolyse in methanol of 1,2-diphenylazispiropentane gives the adduct cyclopropane, whereas anhydrous hydrochloric acid treatment gives cyclobutanimine which may be hydrolysed in aqueous acid into cyclobutanone.

T. Tlili

Pages 3-7

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