Préparation, caractérisation et étude structurale du complexe de cuivre(II) et de cyclohéxenyléthylamine [Cu(C8H15N)4](C8H16N)2(SO4)2.4H2O
Written by sctunisie no commentsThe complex [Cu(C8H15N)4](C8H16N)2(SO4)2.4H2O has been prepared in ethanol solution at room temperature. It has been characterized by scan electronic microscopy and infrared spectroscopy. The structure was determined by single crystal X-ray diffraction. The cell is triclinic P-1, a=6.920(3)Å, b=12.349(4)Å, c=18.326(4)Å, α=106.42(2)°, β=99.38(3)°, γ=90.58(4)° and Z=1. The structure is composed of complex molecules [Cu(C8H15N)4]2+, C8H16N+ ions, sulfate groups and water free molecules. The copper(II) ion has a square plane environment.
L. Cherif, F. Ben Amor, A. Driss, T. Jouini
structure, complex, copper(II)
Pages 267 - 276
